Advanced carbon-fiber composites have been used in recent years to lighten planes’ loads. These materials can match aluminum and titanium in strength but at a fraction of the weight, and can be found in aircraft like the Boeing 787 and Airbus A380, reducing such jets’ weight by 20 percent.
For the next generation of commercial jets, researchers are looking to even stronger and lighter materials, such as composites made with carbon fibers coated with carbon nanotubes — tiny tubes of crystalline carbon. When arranged in certain configurations, nanotubes can be hundreds of times stronger than steel, but only one-sixth the weight, making such composites attractive for use in airplanes, as well as cars, trains, spacecraft and satellites.
But a significant hurdle to achieving such composites lies at the nanoscale: Scientists who have tried growing carbon nanotubes on carbon fibers have found that doing so significantly degrades the underlying fibers, stripping them of their inherent strength.
Now a team from MIT has identified the root cause of this fiber degradation, and devised techniques to preserve the fibers’ strength. Applying their discoveries, the researchers coated carbon fibers with nanotubes without causing fiber degradation, making the fibers twice as strong as previous nanotube-coated fibers — paving the way for carbon-fiber composites that are not only stronger, but also more electrically conductive. The researchers say the techniques can easily be integrated into current fiber-manufacturing processes.
“Up until now, people were basically improving one part of the material but degrading the underlying fiber, and it was a trade-off, you couldn’t get everything you wanted,” says Brian Wardle, an associate professor of aeronautics and astronautics at MIT. “With this contribution, you can now get everything you want.”
A paper detailing the results by Wardle and his colleagues is published in the journal ACS Applied Materials and Interfaces. Co-authors are postdoc Stephen Steiner, who contributed to the research as a graduate student, and Richard Li, a graduate student who was an undergraduate in Wardle’s lab.
Getting to the nitty-gritty of fiber degradation
To understand how carbon fibers are manufactured, the group visited carbon-fiber production plants in Japan, Germany and Tennessee. One aspect of the fiber-manufacturing process stood out: During manufacturing, fibers are stretched to near their breaking point as they are heated to high temperatures. In contrast, researchers who have tried to grow nanotubes on carbon fibers in the lab typically do not use tension in their fabrication processes.